JWST MIRI detected seven carbon-bearing molecules including benzene in CT Cha b’s circumplanetary disk at 625 ly, revealing first moon-formation chemistry.
Gabriele Cugno and Sierra Grant’s Astrophysical Journal Letters study presents JWST MIRI medium-resolution spectroscopy revealing CT Cha b’s circumplanetary disk chemistry: acetylene (C₂H₂), benzene (C₆H₆), diacetylene (C₄H₂), propyne (C₃H₄), ethane (C₂H₆), hydrogen cyanide (HCN), and CO₂—establishing C/O>1. The 17 M_J companion orbits 2-Myr-old T Tauri star at 507 AU, with carbon-rich disk contrasting host star’s water-dominated chemistry, evidencing million-year chemical evolution.
The Curious Discovery of Exomoon-Forming Environments
Circumplanetary disks (CPDs) form via angular momentum conservation during gas giant accretion, providing reservoir material for satellite formation analogous to Jupiter’s Galilean moon origins. Prior to JWST, only ~3 CPD candidates (PDS 70 b/c via Hα emission, ALMA continuum; J1604-2130 AB via mm-wave dust) were tentatively identified, with no compositional characterization due to faintness (<0.01% host star flux at mid-IR) and angular proximity. CT Cha b’s wide 507 AU separation and 17 M_J mass enabled MIRI high-contrast spectroscopy isolating CPD emission from stellar glare through careful PSF subtraction and spectral cross-correlation techniques.
What Happens During High-Contrast MIRI Spectroscopy

MIRI’s medium-resolution spectrograph (MRS) observed CT Cha system at 5–28 μm (R~3,000–1,500) in July 2023 under Cycle 1 GO program. Molecular spectral cross-correlation (SCC) maps identified seven C-bearing species at CT Cha b’s location offset from stellar centroid, while host star CT Cha A showed only H₂O absorption features and no carbon molecules. Detected molecules’ rotational temperatures ranged 600–1,200 K, consistent with CPD inner rim (r<0.5 AU from planet) heating via accretion luminosity L_acc~10⁻⁴ L_☉ plus stellar irradiation. Benzene (C₆H₆) detection at 11.8/12.3 μm and diacetylene (C₄H₂) at 7.9 μm represent first observations in any CPD, previously seen only in protoplanetary disks around low-mass stars like J160532.
Why It Matters for Satellite Formation Chemistry
Jupiter’s Galilean moons exhibit compositional diversity: carbon-poor icy Ganymede/Callisto (rocky cores presumably silicate or carbon) versus differentiated Io/Europa. CT Cha b’s carbon-rich CPD suggests nascent satellites could inherit high C/O>1 compositions, potentially forming Titan-analog carbon-rich atmospheres if volatiles retained during accretion. The stark chemical dichotomy—carbon-dominated CPD versus oxygen-rich (H₂O-bearing, no carbon) circumstellar disk—implies rapid chemical fractionation within 2 Myr via mechanisms including: (1) preferential radial drift carrying oxygen-rich ices inward to accrete onto star, leaving carbon reservoir in outer disk, (2) UV photodissociation destroying oxygen-bearing ices while carbon chains resist fragmentation, (3) carbon grain sublimation in CPD’s warm environment.
Observational Challenges in CPD Characterization
CT Cha b’s contrast ratio ΔK~10 mag relative to host star required iterative PSF modeling subtracting stellar+circumstellar continuum before extracting planetary+CPD spectra. MIRI’s 0.6–1.5 arcsec spatial resolution at 5–28 μm resolves 507 AU (1.8 arcsec) separation, but CPD extent (<1 AU radius around planet) remains spatially unresolved, preventing direct imaging of disk morphology or gap structures. Alternative explanations for detected molecules—atmospheric absorption in CT Cha b’s envelope versus CPD emission—were ruled out via spatial offset consistency and molecular abundance patterns mismatching brown dwarf/exoplanet atmospheric equilibrium chemistry.
Link to Protoplanetary Disk Chemical Trends
The carbon-rich CPD composition follows mass-dependent trends observed in isolated brown dwarfs and very-low-mass stars: disk C/O ratios increase with decreasing host mass from solar-type (C/O~0.5–0.8) to M-dwarfs and brown dwarfs (C/O>1). This suggests universal chemical evolution pathways where gravitational fragmentation mass scales determine oxygen retention efficiency: higher-mass objects efficiently accrete oxygen-rich volatiles early, while lower-mass companions retain carbon-dominated reservoirs. Comparing CT Cha b’s CPD to J160532’s protoplanetary disk (both showing benzene, diacetylene, acetylene dominance with minimal H₂O/CO₂) validates applicability of disk chemistry models across companion mass ranges from ~0.01–20 M_J.
What the Future Holds for Exomoon Searches

Cugno and Grant’s approved JWST Cycle 4 program will survey nine additional wide-separation CPD candidates including PDS 70 b/c, AB Aurigae b, and HIP 99770 b, expanding chemical diversity statistics. ALMA Band 6/7 observations targeting same systems will measure dust mass, grain size distributions, and spatial morphology complementing MIRI gas-phase chemistry, constraining solid-to-gas ratios critical for satellite formation efficiency. Future ELT/METIS high-resolution spectroscopy (R~100,000 at 3–5 μm) will resolve individual molecular lines enabling Doppler velocity mapping to distinguish CPD rotation from planetary atmosphere, potentially detecting forming satellites via gravitational perturbations or photometric transits.
Why This Discovery Is So Exciting for Planetary Science
Characterizing CT Cha b’s CPD provides first empirical constraints on moon-forming environment chemistry, transitioning theoretical satellite formation models from parameter-space explorations to data-driven validation. The carbon-rich composition challenges assumptions that Galilean-analog satellites universally inherit oxygen-rich ice compositions, predicting greater exomoon chemical diversity than previously envisioned. Successfully isolating CPD spectroscopy from stellar+circumstellar backgrounds demonstrates JWST’s capability to study faint planetary-scale disks, opening observational windows to processes—satellite accretion, CPD dispersal timescales, moon-disk interactions—previously accessible only through Solar System retrospective analyses and numerical simulations.
Conclusion
JWST’s detection of benzene and six other carbon molecules in CT Cha b’s circumplanetary disk marks the first direct chemical characterization of a potential exomoon-forming environment, revealing carbon-dominated chemistry contrasting with oxygen-rich protoplanetary disks. As follow-up surveys expand the CPD sample and ALMA observations map disk structures, these findings promise comprehensive understanding of satellite system origins bridging Solar System moon diversity and exoplanetary architectures. Explore more about astronomy and space discoveries on our YouTube channel, So Join NSN Today.



























